
3400-45-1
- Product Name:Cyclopentanecarboxylic acid
- Molecular Formula:C6H10O2
- Purity:99%
- Molecular Weight:114.144
Product Details
Factory Sells Best Quality Cyclopentanecarboxylic acid 3400-45-1 with steady supply
- Molecular Formula:C6H10O2
- Molecular Weight:114.144
- Appearance/Colour:clear colorless to yellow liquid
- Vapor Pressure:0.0626mmHg at 25°C
- Melting Point:3-5 °C(lit.)
- Refractive Index:n20/D 1.453(lit.)
- Boiling Point:213.832 °C at 760 mmHg
- PKA:4.99(at 25℃)
- Flash Point:96.251 °C
- PSA:37.30000
- Density:1.13 g/cm3
- LogP:1.26120
Cyclopentanecarboxylic acid(Cas 3400-45-1) Usage
Synthesis Reference(s) |
The Journal of Organic Chemistry, 37, p. 3381, 1972 DOI: 10.1021/jo00986a054Synthetic Communications, 20, p. 1353, 1990 DOI: 10.1080/00397919008052848 |
Purification Methods |
If it is discoloured shake it with saturated aqueous NaCl, extract it with Et2O, dry the extract (MgSO4), filter, evaporate and distil the residue preferably under a vacuum. The lachrymatory acid chloride has M 114.1, m 4o and b 216o/atm, d4 1.091, nD 1.4620. [Beilstein 9 H 6, 9 IV 11.] |
InChI:InChI=1/C6H10O2/c7-6(8)5-3-1-2-4-5/h5H,1-4H2,(H,7,8)/p-1
3400-45-1 Relevant articles
-
Edwards,Lesage
, p. 2071 (1959)
-
-
Loftfield
, p. 632 (1950)
-
Transformation of Thioacids into Carboxylic Acids via a Visible-Light-Promoted Atomic Substitution Process
Fu, Qiang,Liang, Fu-Shun,Lou, Da-Wei,Pan, Gao-Feng,Wang, Rui,Wu, Min,Xie, Kai-Jun
supporting information, p. 2020 - 2024 (2022/03/31)
A visible-light-promoted atomic substitu...
Gram-scale synthesis of carboxylic acids via catalytic acceptorless dehydrogenative coupling of alcohols and hydroxides at an ultralow Ru loading
Chen, Cheng,Cheng, Hua,Verpoort, Francis,Wang, Zhi-Qin,Wu, Zhe,Yuan, Ye,Zheng, Zhong-Hui
, (2021/12/13)
Acceptorless dehydrogenative coupling (A...
Time-Dependent Self-Assembly of Copper(II) Coordination Polymers and Tetranuclear Rings: Catalysts for Oxidative Functionalization of Saturated Hydrocarbons
Costa, Ines F. M.,Kirillova, Marina V.,André, Vania,Fernandes, Tiago A.,Kirillov, Alexander M.
supporting information, p. 14491 - 14503 (2021/07/19)
This study describes a time-dependent se...
Mild oxidative functionalization of cycloalkanes catalyzed by novel dicopper(II) cores
Trusau, Kiryl I.,Kirillova, Marina V.,André, Vania,Usevich, Andrew I.,Kirillov, Alexander M.
, (2021/02/09)
The search for new transition metal base...
3400-45-1 Process route
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108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

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-
124-04-9
Adipic acid

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-
3400-45-1
cyclopentanecarboxylic acid

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765-87-7
cyclohexane-1,2-dione

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-
533-60-8
cyclohexanone-2-ol
Conditions | Yield |
---|---|
With
manganese(IV) oxide; perchloric acid;
tris(2,2’-bipyridine)ruthenium(II);
for 0.333333h;
Product distribution;
Thermodynamic data;
Rate constant;
in prsence and absence of air; ΔH(act.), ΔG(act.), ΔS(act.);
|
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108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

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-
502-44-3,24980-41-4,80137-66-2
hexahydro-2H-oxepin-2-one

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-
124-04-9
Adipic acid

-
-
1191-25-9
6-Hydroxyhexanoic acid

-
-
3400-45-1
cyclopentanecarboxylic acid
Conditions | Yield |
---|---|
With
tert.-butylhydroperoxide; 2-methyl-1,3,2-benzothiaselenazole 1,1-dioxide;
In
tert-butyl alcohol;
at 65 ℃;
for 15h;
Further Variations:;
Reagents;
Product distribution;
|
3400-45-1 Upstream products
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1-Chlor-7-oxa-bicyclo<4.1.0>heptan
-
ethanol
-
sodium ethanolate
-
cyclopentanecarbonitrile
3400-45-1 Downstream products
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methyl cyclopentane carboxylate
-
cyclopentanecarboxylic acid anhydride
-
cyclopentyl thien-2-yl ketone
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Cyclopentanecarboxylic acid chloride
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