99-97-8

  • Product Name:N,N-Dimethyl-p-toluidine
  • Molecular Formula:C9H13N
  • Purity:99%
  • Molecular Weight:135.209
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Product Details

Chinese Manufacturer supply N,N-Dimethyl-p-toluidine 99-97-8 in stock with high standard

  • Molecular Formula:C9H13N
  • Molecular Weight:135.209
  • Appearance/Colour:light yellow liquid 
  • Vapor Pressure:0.1 hPa (20 °C) 
  • Melting Point:-25°C 
  • Refractive Index:n20/D 1.546(lit.)  
  • Boiling Point:211.6 °C at 760 mmHg 
  • PKA:pK1:7.24(+1) (25°C) 
  • Flash Point:84.2 °C 
  • PSA:3.24000 
  • Density:0.94 g/cm3 
  • LogP:2.06100 

N,N-DIMETHYL-P-TOLUIDINE(Cas 99-97-8) Usage

Synthesis Reference(s)

Synthetic Communications, 19, p. 3051, 1989 DOI: 10.1080/00397918908052700Tetrahedron Letters, 8, p. 1849, 1967

Reactivity Profile

N,N-DIMETHYL-P-TOLUIDINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.

Purification Methods

Reflux for 3hours with 2 molar equivalents of Ac2O, then fractionally distil it under reduced pressure. Alternatively, dry it over BaO, distil and store it over KOH. The picrate has m 128o (from EtOH). Methods described for N,N-dimethylaniline are applicable here. [Beilstein 12 H 902, 12 III 2026, 12 IV 1874.]

General Description

A clear colorless liquid with an aromatic odor. Density 0.937 g / cm3 (Lancaster) and insoluble in water. Hence floats on water. Toxic by skin absorption and inhalation. Flash point 181°F. May release toxic vapors when burned.

InChI:InChI=1/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3

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99-97-8 Process route

N-benzyl-N,N-dimethyl-p-methylanilinium bromide
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benzyl bromide
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benzyl bromide

Dimethyl-p-toluidine
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Dimethyl-p-toluidine

Conditions
Conditions Yield
In chloroform; at 34.9 ℃; Rate constant;
In acetone; at 45 ℃; Rate constant; Equilibrium constant;
methanol
67-56-1

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62-53-3

aniline

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609-72-3

N,N-dimethyl-o-toluidine

N-methyl-p-toluidine
623-08-5

N-methyl-p-toluidine

<i>N</i>,<i>N</i>-dimethyl-aniline
121-69-7,77733-26-7

N,N-dimethyl-aniline

N-methylaniline
100-61-8

N-methylaniline

N,2-dimethylaniline
611-21-2

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Dimethyl-p-toluidine
99-97-8

Dimethyl-p-toluidine

Conditions
Conditions Yield
With monoaluminum phosphate; at 425 ℃; Product distribution; other catalyst, var. temp., var.molar ratio of educts;
31.2 % Chromat.
18.3 % Chromat.
5.1 % Chromat.
8.5 % Chromat.
7.0 % Chromat.
10.0 % Chromat.

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